Heating a gypsum cast to a temperature above 90°C will remove water of
crystallization and strengthen it. This process is called "burning out" the
gypsum, and it is used to remove the remaining moisture and improve the cast's
stability and accuracy.
Gypsum casts are made by mixing plaster of Paris (calcium sulfate hemihydrate)
with water. When the material sets, it forms calcium sulfate dihydrate crystals
with water molecules trapped within the crystal lattice, known as water of
crystallization. Heating the cast above 90°C causes the water of crystallization
to be released, which results in the cast becoming stronger and more rigid. This
process does not cause the cast to expand but rather to shrink slightly as the
water is removed. Excess gauging water is typically removed during the initial
setting process.