NEET MDS Lessons
Dental Materials
Investment Techniques
Single step investing technique:
The investing procedure is carried out in one step either by brush technique or by vacuum technique.
a). Brush technique:
The accurate water-powder ratio is mixed under vacuum. A brush is then used to paint the wax pattern with mix then the casting ring is applied over the crucible former and the ring is filled under vibration until it is completely filled.
b). vacuum technique:
• The mix in first hand spatulated, and then with the crucible former and pattern is place, then ring is attached to the mixing bowl.
• The vacuum hose is then attached to the assembly. The bowel is inverted and the ring is filled under vacuum and vibration
Two-step investing technique:
The investing procedure is carried out in two steps:
• First, the wax pattern is painted with a thick mix andis left till complete setting, the set investment block(first cost) is immersed in water for about tenminutes . the casting ring is then applied over the crucible former and filled with the properly mixedinvestment (second coat) till the ring is completely filled and the mix is left to set.The two-step investing technique is recommendedwhenever greater amount of expansion is required. Thistechnique also minimizes the distortion of the waxpattern and provides castings with smoother surfaces.
• The investment is allowed to set for the recommendedtime (usually one-hour) then the crucible former is removed. If a metal sprue former is used, it is removedby heating over a flame to loosen it from the wax pattern. Any loose particles of investment should beblown off with compressed air should be placed in a humidor if stored overnight.
Zinc Phoshate Cement
Uses. Zinc phosphate cement is used both as an intermediate base and as a cementing medium.
(1) Intermediate base. A thick mix is used under permanent metallic restoration. This layer of cement protects the pulp from sudden temperature changes that may be transmitted by the metallic restoration.
(2) Cementing medium. Zinc phosphate cement is used to permanently cement crowns, inlays, and fixed partial dentures upon the remaining tooth structure. A creamy mix of cement is used to seat the restoration or appliance completely into place. The cementing medium does not cement two objects together. Instead, the cement holds the objects together by mechanical interlocking, filling the space between the irregularities of the tooth preparation and the cemented restoration
c. Chemical Composition.
(1) Powder. primary ingredients - zinc oxide and magnesium oxide.
(2) Liquid. Phosphoric acid and water in the ratio of two parts acid to one part water. The solution may also contain aluminum phosphate and zinc phosphate Liquids exposed in open bottles will absorb moisture from the air in high humidity. The liquids will lose moisture if humidity is low. Water gain hastens setting; water loss lengthens setting time.
PROPERTIES OF ZINC PHOSPHATE CEMENT
a. Advantages. Some advantages of zinc phosphate cement as a cementing medium are:
o Inconspicuous appearance.
o Speed and ease of usage.
o Sufficient flow to form a thin layer for the cementing of closely adapted crowns, fixed partial dentures, and inlays.
o Low thermal conductivity beneath a metallic restoration.
b. Disadvantages. Some disadvantages of zinc phosphate cement as a cementing medium are:
o Low crushing strength that varies between 12,000 and 19,000 psi.
o Slight solubility in mouth fluids.
o Opaque material not suitable for visible surfaces.
c. Strength. The ratio of powder to liquid increases the strength of phosphate cements to a certain point. For this reason, the dental specialist must use as thick a mix as practical for the work being performed.
SETTING REACTIONS OF ZINC PHOSPHATE CEMENT
a. Chemical Reaction. The chemical reaction that takes place between the powder and liquid of setting phosphate cement produces heat. The amount of heat produced depends upon the rate of reaction, the size of the mix, and the amount of heat extracted by the mixing slab.
b. Powder to Liquid Ratio. The less powder used in ratio to the liquid, the longer the cement will take to harden. Good technique minimizes the rise in temperature and acidity of the setting cement that can injure the pulp. Generally, for increased strength, decreased shrinkage, and resistance to solubility, it is advisable to blend as much powder as possible to reach the desired consistencies.
c. Setting Time. The setting time of zinc phosphate cement is normally between 5 and 9 minutes.
Lower the temperature of the glass mixing slab to between 65° and 75° F (18° to 24° C), if the glass mixing slab is not already cooled below the temperature at which moisture will condense on it. → Blend the powder slowly. → Mix the powder over a large area of the cool slab. → Use a longer mixing time, within optimum limits.
Precautions. The following precautions should be observed.
o Prevent loss or gain of moisture in liquid cement by keeping bottles tightly stoppered.
o Dispense drops only when ready to mix.
o Use a cool, dry glass slab (65° to 75° F).
o Use the same brand of powder and liquid.
o Add increments of powder slowly.
o Use the maximum amount of powder to obtain the desired consistency.
(To incorporate the most powder, the material should be mixed with a moderate circular motion over a large area of the slab, turning the spatula often.)
Investment Materials
Investment is mold-making material
Applications
a. Mold-making materials for casting alloys
b. Mold-making materials for denture production
Classification
a. Gypsum-bonded investments (based on gypsum products for matrix)
b. Phosphate-bonded investments
c. Silicate-bonded investments
Components
a. Liquid-water or other reactant starts formation of matrix binder by reacting with reactant powder
b. Powder-reactant powder, filler, or modifiers
Manipulation
a. P/L mixed and placed in container around wax pattern
b. After setting, the investment is heated to eliminate the wax pattern in preparation for casting
METALLURGICAL TERMS
a. Cold Working. This is the process of changing the shape of a metal by rolling, pounding, bending, or twisting at normal room temperature.
b. Strain Hardening. This occurs when a metal becomes stiffer and harder because of continued or repeated application of a load or force. At this point, no further slippage of the atoms of the metal can occur without fracture.
c. Heat Softening Treatment (Annealing). This treatment is necessary in order to continue manipulating a metal after strain hardening to prevent it from fracturing. The process of annealing consists of heating the metal to the proper temperature (as indicated by the manufacturer's instructions) and cooling it rapidly by immersing in cold water. Annealing relieves stresses and strains caused by cold working and restores slipped atoms within the metal to their regular arrangement.
d. Heat Hardening Treatment (Tempering). This treatment is necessary to restore to metals properties that are decreased by annealing and cold working. Metals to be heat hardened should first be heat softened (annealed) so that all strain hardening is relieved and the hardening process can be properly controlled. Heat hardening is accomplished in dental gold alloy by heating to 840o Fahrenheit, allowing it to cool slowly over a 15-minute period to 480o Fahrenheit, and then immersing it in water.
Stages of manipulation
Definitions of intervals
- Mixing interval-length of time of the mixing stage.
- Working interval-length of time of the working stage
- Setting interval-length of time of the setting stage
Definitions of times
- Mixing time-the elapsed time from the onset to the completion of mixing
- Working time-the elapsed time from the onset of mixing until the onset of the initial setting time
- Initial setting time-time at which sufficient reaction has occurred to cause the materials to be resistant to further manipulation
- Final setting time-time at which the material practically is set as defined by its resistance to indentation
[All water-based materials lose their gloss at the time of setting]
Properties-improve with filler content
Physical
Radiopacity depends on ions in silicate glass or the addition of barium sulfate (many systems radiolucent)
Coefficient of thermal expansion is 35 to 45 ppm/C and decreases with increasing filler content
Thermal and electrical insulators
Chemical
Water absorption is 0.5 % to 2.5% and increases with polymer level)
Acidulated topical fluorides (e.g., APF) tend to dissolve glass particles, and thus composites should be protected with petroleum jelly (Vaseline) during those procedures
Color changes occur in resin matrix with time because of oxidation, which produces colored by-products
Mechanical
Compressive strength is 45,000 to 60,000 lb/ in2, which is adequate
Wear resistance-improves with higher filler content, higher percentage of conversion in curing, and use of microfiller, but it is not adequate for some posterior applications
Surfaces rough from wear retain plaque and stain more readily
Biologic
Components may be cytotoxic, but cured composite is biocompatible as restorative filling material
COMPOSITE RESINS
Applications / Use
- Anterior restorations for aesthetics (class III, IV, V, cervical erosion abrasion lesions)
- Low-stress posterior restorations (small class I, II)
- Veneers
- Cores for cast restorations
- Cements for porcelain restorations
- Cements for acid-etched Maryland bridges
- Repair systems for composites or porcelains
Polymerization--reaction of small molecules (monomers) into very large molecules (polymers)
Cross-linking-tying together of polymer molecules by chemical reaction between the molecules to produce a continuous three-dimensional network
Reaction
a. Calcium sulfate hemihydrate(one-half water) crystals dissolve and react with water
b. Calcium sulfate dihydrate(two waters) form and precipitate new crystals
c. Unreacted (excess) water is left between crystals in solid