Amalgam Bonding Agents

Amalgam bonding agents can be classified into several categories based on their composition and mechanism of action:

A. Adhesive Systems

• Total-Etch Systems: These systems involve etching both enamel and dentin with phosphoric acid to create a rough surface that enhances mechanical retention. After etching, a bonding agent is applied to the prepared surface before the amalgam is placed.
• Self-Etch Systems: These systems combine etching and bonding in one step, using acidic monomers that partially demineralize the tooth surface while simultaneously promoting bonding. They are less technique-sensitive than total-etch systems.

B. Glass Ionomer Cements

• Glass ionomer cements can be used as a base or liner under amalgam restorations. They bond chemically to both enamel and dentin, providing a good seal and some degree of fluoride release, which can help in caries prevention.

C. Resin-Modified Glass Ionomers

• These materials combine the properties of glass ionomer cements with added resins to improve their mechanical properties and bonding capabilities. They can be used as a liner or base under amalgam restorations.

Mechanism of Action

A. Mechanical Retention

• Amalgam bonding agents create a roughened surface on the tooth structure, which increases the surface area for mechanical interlocking between the amalgam and the tooth.

B. Chemical Bonding

• Some bonding agents form chemical bonds with the tooth structure, particularly with dentin. This chemical interaction can enhance the overall retention of the amalgam restoration.

C. Sealing the Interface

• By sealing the interface between the amalgam and the tooth, bonding agents help prevent microleakage, which can lead to secondary caries and postoperative sensitivity.

Applications of Amalgam Bonding Agents

A. Sealing Tooth Preparations

• Bonding agents are used to seal the cavity preparation before the placement of amalgam, reducing the risk of microleakage and enhancing the longevity of the restoration.

B. Bonding New to Old Amalgam

• When repairing or replacing an existing amalgam restoration, bonding agents can be used to bond new amalgam to the old amalgam, improving the overall integrity of the restoration.

C. Repairing Marginal Defects

• Bonding agents can be applied to repair marginal defects in amalgam restorations, helping to restore the seal and prevent further deterioration.

Clinical Considerations

A. Technique Sensitivity

• The effectiveness of amalgam bonding agents can be influenced by the technique used during application. Proper surface preparation, including cleaning and drying the tooth structure, is essential for optimal bonding.

B. Moisture Control

• Maintaining a dry field during the application of bonding agents is critical. Moisture contamination can compromise the bond strength and lead to restoration failure.

C. Material Compatibility

• It is important to ensure compatibility between the bonding agent and the amalgam used. Some bonding agents may not be suitable for all types of amalgam, so clinicians should follow manufacturer recommendations.

D. Longevity and Performance

• While amalgam bonding agents can enhance the performance of amalgam restorations, their long-term effectiveness can vary. Regular monitoring of restorations is essential to identify any signs of failure or degradation.

Pouring the Final Impression

Technique

• Mixing Die Stone: A high-strength die stone is mixed using a vacuum mechanical mixer to ensure a homogenous mixture without air bubbles.
• Pouring Process:
  • The die stone is poured into the impression using a vibrator and a No. 7 spatula.
  • The first increments should be applied in small amounts, allowing the material to flow into the remote corners and angles of the preparation without trapping air.
• Surface Tension-Reducing Agents: These agents can be added to the die stone to enhance its flow properties, allowing it to penetrate deep into the internal corners of the impression.

Final Dimensions

• The impression should be filled sufficiently so that the dies will be approximately 15 to 20 mm tall occluso-gingivally after trimming. This height is important for the stability and accuracy of the final restoration.

Carisolv

Carisolv is a dental caries removal system that offers a unique approach to the treatment of carious dentin. It differs from traditional methods, such as Caridex, by utilizing amino acids and a lower concentration of sodium hypochlorite. Below is an overview of its components, mechanism of action, application process, and advantages.

1. Components of Carisolv

A. Red Gel (Solution A)

• Composition:
  • Amino Acids: Contains 0.1 M of three amino acids:
    • I-Glutamic Acid
    • I-Leucine
    • I-Lysine
  • Sodium Hydroxide (NaOH): Used to adjust pH.
  • Sodium Hypochlorite (NaOCl): Present at a lower concentration compared to Caridex.
  • Erythrosine: A dye that provides color to the gel, aiding in visualization during application.
  • Purified Water: Used as a solvent.

B. Clear Liquid (Solution B)

• Composition:
  • Sodium Hypochlorite (NaOCl): Contains 0.5% NaOCl w/v, which contributes to the antimicrobial properties of the solution.

C. Storage and Preparation

• Temperature: The two separate gels are stored at 48°C before use and are allowed to return to room temperature prior to application.

2. Mechanism of Action

• Softening Carious Dentin: Carisolv is designed to soften carious dentin by chemically disrupting denatured collagen within the affected tissue.
• Collagen Disruption: The amino acids in the formulation play a crucial role in breaking down the collagen matrix, making it easier to remove the softened carious dentin.
• Scraping Away: After the dentin is softened, it is removed using specially designed hand instruments, allowing for precise and effective caries removal.

3. pH and Application Time

• Resultant pH: The pH of Carisolv is approximately 11, which is alkaline and conducive to the softening process.
• Application Time: The recommended application time for Carisolv is between 30 to 60 seconds, allowing for quick treatment of carious lesions.

4. Advantages

• Minimally Invasive: Carisolv offers a minimally invasive approach to caries removal, preserving healthy tooth structure while effectively treating carious dentin.
• Reduced Need for Rotary Instruments: The chemical action of Carisolv reduces the reliance on traditional rotary instruments, which can be beneficial for patients with anxiety or those requiring a gentler approach.
• Visualization: The presence of erythrosine allows for better visualization of the treated area, helping clinicians ensure complete removal of carious tissue.

Various dyes have been tried to detect carious enamel, each having some Advantages and Disadvantages:

‘Procion’ dyes stain enamel lesions but the staining becomes irreversible because the dye reacts with nitrogen and hydroxyl groups of enamel and acts as a fixative.

‘Calcein’ dye makes a complex with calcium and remains bound to the lesion.

‘Fluorescent dye’ like Zyglo ZL-22 has been used in vitro which is not suitable in vivo. The dye is made visible by ultraviolet illumination.

Cutting Edge Mechanics

Edge Angles and Their Importance

• Edge Angle: The angle formed at the cutting edge of a bur blade. Increasing the edge angle reinforces the cutting edge, which helps to reduce the likelihood of blade fracture during use.
• Reinforcement: A larger edge angle provides more material at the cutting edge, enhancing its strength and durability.

Carbide vs. Steel Burs

• Carbide Burs:
  • Hardness and Wear Resistance: Carbide burs are known for their higher hardness and wear resistance compared to steel burs. This makes them suitable for cutting through hard dental tissues.
  • Brittleness: However, carbide burs are more brittle than steel burs, which means they are more prone to fracture if not designed properly.
  • Edge Angles: To minimize the risk of fractures, carbide burs require greater edge angles. This design consideration is crucial for maintaining the integrity of the bur during clinical procedures.

Interdependence of Angles

• Three Angles: The cutting edge of a bur is defined by three angles: the edge angle, the clearance angle, and the rake angle. These angles cannot be varied independently of each other.
  • Clearance Angle: An increase in the clearance angle (the angle between the cutting edge and the surface being cut) results in a decrease in the edge angle. This relationship is important for optimizing cutting efficiency and minimizing wear on the bur.

_{Fillers in Conservative Dentistry}

_{Fillers play a crucial role in the formulation of composite resins used in conservative dentistry. They are inorganic materials added to the organic matrix to enhance the physical and mechanical properties of the composite. The size and type of fillers significantly influence the performance of the composite material.}

_{1. Types of Fillers Based on Particle Size}

_{Fillers can be categorized based on their particle size, which affects their properties and applications:}

• _{Macrofillers: 10 - 100 µm}
• _{Midi Fillers: 1 - 10 µm}
• _{Minifillers: 0.1 - 1 µm}
• _{Microfillers: 0.01 - 0.1 µm}
• _{Nanofillers: 0.001 - 0.01 µm}

_{2. Composition of Fillers}

_{The dispersed phase of composite resins is primarily made up of inorganic filler materials. Commonly used fillers include:}

• _{Silicon Dioxide}
• _{Boron Silicates}
• _{Lithium Aluminum Silicates}

_{A. Silanization}

• _{Filler particles are often silanized to enhance bonding between the hydrophilic filler and the hydrophobic resin matrix. This process improves the overall performance and durability of the composite.}

_{3. Effects of Filler Addition}

_{The incorporation of fillers into composite resins leads to several beneficial effects:}

• _{Reduces Thermal Expansion Coefficient: Enhances dimensional stability.}
• _{Reduces Polymerization Shrinkage: Minimizes the risk of gaps between the restoration and tooth structure.}
• _{Increases Abrasion Resistance: Improves the wear resistance of the restoration.}
• _{Decreases Water Sorption: Reduces the likelihood of degradation over time.}
• _{Increases Tensile and Compressive Strengths: Enhances the mechanical properties, making the restoration more durable.}
• _{Increases Fracture Toughness: Improves the ability of the material to resist crack propagation.}
• _{Increases Flexural Modulus: Enhances the stiffness of the composite.}
• _{Provides Radiopacity: Allows for better visualization on radiographs.}
• _{Improves Handling Properties: Enhances the workability of the composite during application.}
• _{Increases Translucency: Improves the aesthetic appearance of the restoration.}

_{4. Alternative Fillers}

_{In some composite formulations, quartz is partially replaced with heavy metal particles such as:}

• _Zinc
• _Aluminum
• _Barium
• _Strontium
• _Zirconium

_{A. Calcium Metaphosphate}

• _{Recently, calcium metaphosphate has been explored as a filler due to its favorable properties.}

_{B. Wear Considerations}

• _{These alternative fillers are generally less hard than traditional glass fillers, resulting in less wear on opposing teeth.}

_{5. Nanoparticles in Composites}

_{Recent advancements have introduced nanoparticles into composite formulations:}

• _{Nanoparticles: Typically around 25 nm in size.}
• _{Nanoaggregates: Approximately 75 nm, made from materials like zirconium/silica or nano-silica particles.}

_{A. Benefits of Nanofillers}

• _{The smaller size of these filler particles results in improved surface finish and polishability of the restoration, enhancing both aesthetics and performance.}