NEET MDS Lessons
Dental Materials
Classification
Rigid impression materials
(1) Plaster
(2) Compound
(3) Zinc oxide-eugenol
Flexible hydrocolloid impression materials
(I) Agar-agar (reversible hydrocolloid)
(2) Alginate (irreversible hydrocolloid)
Flexible, elastomeric, or rubber impression materials
(1) Polysulfide rubber (mercaptan rubber)
(2) Silicone rubber (condensation silicone)
(3) Polyether rubber
(4) Polyvinyl siloxane (addition silicone)
Investment Techniques
Single step investing technique:
The investing procedure is carried out in one step either by brush technique or by vacuum technique.
a). Brush technique:
The accurate water-powder ratio is mixed under vacuum. A brush is then used to paint the wax pattern with mix then the casting ring is applied over the crucible former and the ring is filled under vibration until it is completely filled.
b). vacuum technique:
• The mix in first hand spatulated, and then with the crucible former and pattern is place, then ring is attached to the mixing bowl.
• The vacuum hose is then attached to the assembly. The bowel is inverted and the ring is filled under vacuum and vibration
Two-step investing technique:
The investing procedure is carried out in two steps:
• First, the wax pattern is painted with a thick mix andis left till complete setting, the set investment block(first cost) is immersed in water for about tenminutes . the casting ring is then applied over the crucible former and filled with the properly mixedinvestment (second coat) till the ring is completely filled and the mix is left to set.The two-step investing technique is recommendedwhenever greater amount of expansion is required. Thistechnique also minimizes the distortion of the waxpattern and provides castings with smoother surfaces.
• The investment is allowed to set for the recommendedtime (usually one-hour) then the crucible former is removed. If a metal sprue former is used, it is removedby heating over a flame to loosen it from the wax pattern. Any loose particles of investment should beblown off with compressed air should be placed in a humidor if stored overnight.
Manipulation
Mixing
o P/L types mixed in bowl (plaster and alginate)
o Thermoplastic materials not mixed (compound and agar-agar)
o Paste/paste types hand mixed on pad (zinc oxide-eugenol, polysulfide rubber, silicone rubber, polyether rubber. and poly-vinylsiloxane)
o Paste/paste mixed through a nozzle on an auto-mixing gun (poly-vinylsiloxane)
Placement
o Mixed material carried in tray to mouth (full arch tray, quadrant tray. or triple tray)
o Materials set in mouth more quickly because of higher temperature
Removal - rapid removal of impression encourages deformation to take place elastically rather than permanently (elastic deformation requires about 20 minutes)
Cleaning and disinfection of impressions
Principles of cutting, polishing, and surface cleaning
- Surface mechanics for materials
Cutting-requires highest possible hardness materials to produce cutting
Finishing-requires highest possible hardness materials to produce finishing, except at margins of restorations where tooth structure may be inadvertently affected
Polishing- requires materials with Mohs ./ hardness that is 1 to 2 units above that of substrate
Debriding-requires materials with Mohs hardness that is less than or equal to that of substrate to prevent scratching
- Factors affecting cutting, polishing. and surface cleaning
- Applied pressure
- Particle size of abrasive
- Hardness of abrasive
- Hardness of substrate
- Precautions
- During cutting heat will build up and change the mechanical behavior of the substrate from brittle to ductile and encourage smearing
- Instruments may transfer debris onto the cut surface from their own surfaces during cutting, polishing, or cleaning operations (this is important for cleaning implant surfaces)
Mechanical properties
1. Resolution of forces
Uniaxial (one-dimensional) forces-compression, tension, and shear
Complex forces-torsion, flexion. And diametral
2. Normalization of forces and deformatations
Stress
Applied force (or material’s resistance to force) per unit area
Stress-force/area (MN/m2)
Strain
Change in length per unit of length because of force
Strain-(L- Lo)/(Lo); dimensionless units
3. Stress-strain diagrams
Plot of stress (vertical) versus strain (horizontal)
- Allows convenient comparison of materials
- Different curves for compression, tension, and shear
- Curves depend on rate of testing and temperature
4. Analysis of curves
- Elastic behavior
- Initial response to stress is elastic strain
- Elastic modulus-slope of first part of curve and represents stiffness of material or the resistance to deformation under force
- Elastic limit (proportional limit)- stress above which the material no longer behaves totally elastically
- Yield strength-stress that is an estimate of the elastic limit at 0.002 permanent strain
- Hardness-value on a relative scale that estimates the elastic limit in terms of a material’s resistance to indentation (Knoop hardness scale, Diamond pyramid, Brinnell, Rockwell hardness scale, Shore A hardness scale, Mohs hardness scale
- Resilience-area under the stress strain curve up to the elastic limit (and it estimates the total elastic energy that can be absorbed before the onset of plastic deformation)
- Elastic and plastic behavior
- Beyond the stress level of the elastic limit, there is a combination of elastic and plastic strain
- Ultimate strength-highest stress reached before fracture; the ultimate compressive strength is greater than the ultimate shear strength and the ultimate tensile strength
- Elongation (percent elongation)- percent change in length up to the point of fracture = strain x 100%
- Brittle materials-<5% elongation at fracture
- Ductile materials->5% elongation at fracture
- Toughness-area under the stress strain curve up to the point of fracture (it estimates the total energy absorbed up to fracture)
- Time-dependent behavior
the faster a stress is applied, the more likely a material is to store the energy elastically and not plastically
- Creep-strain relaxation
- Stress relaxation
Wax elimination (burnout):
Wax elimination or burnout consists of heating the investment in a thermostatically controlled furnace until all traces of the wax are vaporized in order to obtain an empty mold ready to receive the molten alloy during procedure.
• The ring is placed in the furnace with the sprue hole facing down to allow for the escape of the molten wax out freely by the effect of gravity .
• The temperature reached by the investment determines thethermal expansion. The burnout temperature is slowly increased in order to eliminate the wax and water without cracking the investment.
•For gypsum bonded investment, the mold is heated to650 -6870 c )to cast precious and semiprecious
precious alloys.
• Whereas for phosphate-bonded investment, the mold is heated up to 8340 c to cast nonprecious alloys at high fusing temperature.
The ring should be maintained long enough at the maximum temperature (“heat soak”) to minimize a sudden drop in temperature upon removal from the oven. Such a drop could result in an incomplete casting because of excessively rapid solidification of thealloy as it enters the mold.
• When transferring the casting ring to casting, a quick visual check of the sprue in shaded light is helpful to see whether it is properly heated. It should be a cherry-red color .
WAX BURNOUT AND HEATING THE RING
After the investment has set hard, the crucible former and the metal sprue former is removed carefully, and any loose particles at the opening of the sprue hole are removed with small brush.
The purpose of the wax burnout is to make room for the liquid metal. The ring is placed in the oven at 250C with the sprue end down, thus allowing the melted wax to flow, out for 30min or even up to 60min may be a good procedure to ensure complete elimination of the wax and the carbon.
Heating the ring: The object is to create a mold of such dimension, condition and temperature so that it is best suited to receive the metal.
Hygroscopic Low-Heat Technique.
After the wax elimination the temperature of the same furnace can be set to a higher temperature for heating or else, the ring can be transferred to another furnace, which has already set to the higher temperature. In any case accurate temperature control is essential and therefore these furnaces have pyrometer and thermocouple arrangement. The ring is placed in the furnace with the sprue hole down and heated to 500C and kept at this temperature for 1 hour. In this low heat technique the thermal expansion obtained is less but together with the previously obtained hygroscopic expansion the total expansion amounts to 2.2 percent, which is slightly higher than what is required for gold alloys.
So this technique obtains its compensation expansion from three sources:
(1) The 37º C water bath expands the wax pattern
(2) The warm water entering the investment mold from the top adds some hygroscopic expansion
(3) The thermal expansion at 500' C provides the needed thermal expansion.
High-Heat Thermal Expansion Technique.
After the wax elimination, the ring should be placed in the furnace which is at room temperature and then the temperature is gradually raised, until it comes to 700C in 1 hour. Then the ring is heat soaked at this temperature for ½ hour. This slow rise in temperature is necessary to prevent
This approach depends almost entirely on high-heat burnout to obtain the required expansion, while at the same time eliminating the wax pattern. Additional expansion results from the slight heating of gypsum investments on setting, thus expanding the wax pattern, and the water entering the investment from the wet liner, which adds a small amount of hygroscopic expansion to the normal setting expansion.
WETTABILITY
To minimise the irregularities on the investment & the casting a wetting agent can be used .
FUNCTIONS OF A WETTING AGENT
1 . Reduce contact angle between liquid & wax surface .
2 .Remove any oily film left on wax pattern .