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Dental Materials

PROPERTY

INGREDIENT

 

Silver

Tin

Copper

Zinc

Strength

Increases

 

 

 

Durability

Increases

 

 

 

Hardness

 

 

Increases

 

Expansion

Increases

Decreases

Increases

 

Flow

Decreases

Increases

Decreases

 

Color

Imparts

 

 

 

Setting time

Decreases

Increases

Decreases

 

Workability

 

Increases

 

Increases

 

 

Applications

a. Dentulous impressions for casts for prosthodontics

b. Dentulous impressions for pedodontic appliances

c. Dentulous impressions for study models for orthodontics

d. Edentulous impressions for casts for denture construction

Casting Alloys

Applications-inlay, onlay,  crowns, and bridges

Terms

a. Precious-based on valuable elements
b. Noble or immune-corrosion-resistant element or alloy
c. Base or active-corrosion-prone alloy
d. Passive -corrosion resistant because of surface oxide film
e. Karat (24 karat is 100% gold; 18 karat is 75% gold)
f. Fineness (1000 fineness is I00% gold; 500 fineness is 50% gold)

Classification

High-gold alloys are > 75% gold or other noble metals

Type 1-    83% noble metals (e.g., in simple inlays)
Type II-≥78% noble metals (e.g.,in inlays and onlays)
Type IlI-≥75% noble metals (e.g., in crowns and bridges)
Type IV-≥75% noble metals (e.g., in partial dentures)

Medium-gold alloys are 25% to 75% gold or other noble metals

Low-gold alloys are <25% gold or other noble metals

Gold-substitute alloys arc alloys not containing gold

(1) Palladium-silver alloys-passive .because of mixed oxide film
(2) Cobalt-chromium alloys-passive because of Cr203 oxide film
(3) Iron-chromium alloys-passive because of Cr203 oxide film

Titanium alloys are based on 90% to 100% titanium ; passive because of TiO2 oxide film

Components of gold alloys

-    Gold contributes to corrosion resistance
-    Copper contributes to hardness and strength
-    Silver counteracts orange color of copper
-   Palladium increases melting point and hardness
-    Platinum increases melting point
-    Zinc acts as oxygen scavenger during casting

Manipulation

-    Heated to just beyond melting temperature for casting
o    Cooling shrinkage causes substantial contraction

Properties

Physical

-    Electrical and thermal conductors
-   Relatively low coefficient of thermal expansion

Chemical

-    Silver  content affects susceptibility to tarnish
-   Corrosion resistance  is attributable to nobility or passivation

Mechanical

-   High tensile and compressive strengths but relatively weak in thin sections, such as margins, and can be deformed relatively easily
-    Good wear resistance except in contact with Porcelain
 

Denture Teeth

Use-complete or partial dentures

Type

a. Porcelain teeth
b. Acrylic resin teeth
c. Abrasion-resistant teeth (microfilled composite)

Structure and properties

1. Porcelain teeth (high-fusing porcelain)
Only bonded into denture base mechanically. Harder than natural teeth or other restorations and abrades those surfaces. Good aesthetics.Used when patients have good ridge support and sufficient room between the arches

2. Acrylic resin teeth (PMMA  [polymethyl methacrylate])

Bonded pseudochemically into the denture base. Soft and easily worn by abrasive foods . Good initial aesthetics
Used with patients with poor ridges and in cases where they oppose natural teeth

3. Abrasion-resistant teeth (microfilled resins)
Bonded pseudochemically into the denture base.Better abrasion resistance then  acrylic resin teeth
 

Impression Material

 

 

Materials

Type

Reaction

Composition

Manipulation

Initial setting time

 

Plaster

Rigid

Chemical

Calcuim sulfate hemihydrate, water

Mix P/L in bowl

3-5 min

 

Compound

Rigid

Physical

Resins, wax, stearic acid, and fillers

Soften by heating

 

Variable (sets on

cooling)

Zinc oxide-eugonel

Rigid

Chemical

Zinc oxide powder, oils, eugenol, and

resin

Mix pastes on pad

 

3-5 min

 

Agar-agar

Flexible

Physical

12-15% agar, borax, potassium sulfate,

and 85% water

Mix P/L in bowl

 

Variable (sets on

cooling)

 

alginate

Flexible

Chemical

Sodium alginate, calcium sulfate, retarders,

and 85% water

Mix P/L in bowl

 

4-5 min

 

Polysulfide

Flexible

Chemical

Low MW mercaptan polymer, fillers, lead

dioxide, copper hydroxide, or peroxides

Mix pastes on pad

 

5-7 min

 

Silicone

Flexible

Chemical

Hydroxyl functional dimethyl siloxane, fillers,

tin octoate, and orthoethyl silicate

Mix pastes on pad

 

4.5 min

 

Polyether

Flexible

Chemical

Aromatic sulfonic acid ester and polyether

with ethylene imine groups

Mix pastes on pad

 

2-4 min

 

Polyvinyl siloxane

Flexible

Chemical

Vinyl silicone, filler, chloroplatinic acid,

low MW silicone, and filler

Mix putty or use

two-component

mixing gun

 

4-5 min

 

 

 

 

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