RINGLESS INVESTMENT TECHNIQUE
Used for phosphate bonded investments .
This method uses paper or plastic casting ring .
It is designed to allow urestricted expansion .
Useful for high melting alloys .

POLYCARBOXYLATE CEMENT 

Use:. The primary use of polycarboxylate cement is as a cementing medium of cast alloy and porcelain restorations. In addition, it can be used as a cavity liner, as a base under metallic restorations, or as a temporary restorative material. 

Clinical Uses

Polycarboxylate cement is used in the same way as zinc phosphate cement, both as an intermediate base and as a cementing medium. 

c. Chemical Composition. 

(1) Powder:. It generally contains zinc oxide, 1 to 5 percent magnesium oxide, and 10 to 40 percent aluminum oxide or other reinforcing fillers. A small percentage of fluoride may be included. 
(2) Liquid. Polycarboxylate cement liquid is approximately a 40 percent aqueous solution of polyacrylic acid copolymer with other organic acids such as itaconic acid. Due to its high molecular weight, the solution is rather thick (viscous). 

d. Properties. 

The properties of polycarboxylate cement are identical to those of zinc phosphate cement with one exception. Polycarboxylate cement has lower compressive strength. 

e. Setting Reactions: 

The setting reaction of polycarboxylate cement produces little heat. This has made it a material of choice. Manipulation is simpler, and trauma due to thermal shock to the pulp is reduced. The rate of setting is affected by the powder-liquid ratio, the reactivity of the zinc oxide, the particle size, the presence of additives, and the molecular weight and concentration of the polyacrylic acid. The strength can be increased by additives such as alumina and fluoride. The zinc oxide reacts with the polyacrylic acid forming a cross-linked structure of zinc polyacrylate. The set cement consists of residual zinc oxide bonded together by a gel-like matrix. 

Precautions. 
The following precautions should be observed. 
o    The interior of restorations and tooth surfaces must be free of saliva. 
o    The mix should be used while it is still glossy, before the onset of cobwebbing. 
o    The powder and liquid should be stored in stoppered containers under cool conditions. Loss of moisture from the liquid will lead to thickening. 
 

Mechanical properties

1.  Resolution of forces

Uniaxial (one-dimensional) forces-compression, tension, and shear

Complex forces-torsion, flexion. And diametral

2. Normalization of forces and deformatations

Stress

 Applied force (or material’s resistance to force) per unit area

Stress-force/area (MN/m²)

Strain

Change in length per unit of length because of force

Strain-(L- L_o)/(L_o); dimensionless units

3. Stress-strain diagrams

Plot of stress (vertical) versus strain (horizontal)

• Allows convenient comparison of materials
• Different curves for compression, tension, and shear
• Curves depend on rate of testing and temperature

4. Analysis of curves

• Elastic behavior
  • Initial response to stress is elastic strain
  • Elastic modulus-slope of first part of curve and represents stiffness of material or the resistance to deformation under force
  • Elastic limit (proportional limit)- stress above which the material no longer behaves totally elastically
  • Yield strength-stress that is an estimate of the elastic limit at 0.002 permanent strain
  • Hardness-value on a relative scale that estimates the elastic limit in terms of a material’s resistance to indentation (Knoop hardness scale, Diamond pyramid, Brinnell, Rockwell hardness scale, Shore A hardness scale, Mohs hardness scale

• Resilience-area under the stress strain curve up to the elastic limit (and it estimates the total elastic energy that can be absorbed before the onset of plastic deformation)

• Elastic and plastic behavior

• Beyond the stress level of the elastic  limit, there is a combination of elastic  and plastic strain
• Ultimate strength-highest stress  reached before fracture; the ultimate compressive strength is greater than the ultimate shear strength and the ultimate tensile strength
• Elongation (percent elongation)- percent change in length up to the point of fracture = strain x 100%

• Brittle materials-<5% elongation at fracture

• Ductile materials->5% elongation  at fracture
• Toughness-area under the stress strain  curve up to the point of fracture (it estimates the total energy absorbed up to fracture)

• Time-dependent behavior

the faster a stress is applied, the more likely a material is to store the energy elastically and not plastically

• Creep-strain relaxation
• Stress relaxation

Introduction

The science of dental materials involves a study of the composition and properties of materials and the way in which they interact with the environment in which they are placed

Selection of Dental materials

The process of materials selection should ideally follow a logical sequence involving

(1) analysis of the problem,

(2) consideration of requirements,

(3) consideration of available materials and their properties, leading to

(4) choice of material.

Evaluation of the success or failure of a material may be used to influence future decisions on materials selection.

Temporary Filling Materials

Applications / Use

While waiting for lab fabrication of cast restoration
While observing reaction of pulp tissues

Objectives

Provide pulpal protection
Provide medication to reduce pulpal inflammation
Maintain the tooth position with an aesthetic restoration

Classification

Temporary filling cements
Temporary filling resins

Components

Temporary filling cements

1. Zinc oxide-eugenol cement with cotton fibers added
2. Polyme r powder-reinforced zinc oxide eugenol cement

Temporary filling resins

•    MMA / PMMA filling materials
•    Polyamide filling materials
•    BIS-GMA filling materials
 

Mercury bioactivity

• Metallic mercury is the least toxic from and is absorbed primarily through the lungs rather than the GI tract or skin
• Mercury in the body may come from air, water, food. dental (a low amount). Or medical sources
•  Half life for mercury elimination from body is 55 days .-
• mercury toxicity is <50 µm / m³ on average per 40-hour work week.
• Mercury hypersensitivity is estimated as less than 1 per 100,000,000 persons
• Indium-containing amalgams can have lower Hg vapor pressures than conventional dental amalgam