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Dental Materials

Physical reaction-cooling causes reversible hardening

Chemical reaction-irreversible reaction during setting

Applications/Use

  • Load -bearing restorations for posterior  teeth  (class I, II)
  • Pinned restorations
  • Buildups or cores for cast restorations
  • Retrograde canal filling material

 

 (1) Alloy. An alloy is a solid mixture of two or more metals. It is possible to produce a material in which the desirable properties of each constituent are retained or even enhanced, while the less desirable properties are reduced or eliminated.

(2) Amalgam. When one of the metals in an alloy mixture is mercury, an amalgam is formed. A dental amalgam is a combination of mercury with a specially prepared silver alloy, which is used as a restorative material.

(3) Mercury. Mercury is a silver-white, poisonous, metallic element that is liquid at room temperature

Mercury hygiene

  • Do not contact mercury with skin
  • Clean up spills to minimize mercury vaporization
  • Store mercury or precapsulated products in tight containers
  • Only triturate amalgam components-in tightly- sealed capsules
  • Use amalgam with covers
  • Store spent amalgam under water or fixer in a tightly sealed jar
  • Use high vacuum suction during amalgam alloy placement, setting, or removal when mercury may be vaporized
  • Polishing amalgams generally causes localized melting of silver-mercury phase with release of mercury vapor, so water cooling and evacuation must be used

COMPOSITE RESINS

Types

  • Amount of filler-25% to 65% volume, 45% to 85% weight
  • Filler particle size (diameter in microns)
    • Macrofill 10 to 100 µm (traditional composites)
    • Midi fill- 1 to 10 µm(small particle composites)
    • Minifill— 0.l to 1 µm
    • Microfill-: 0.01 to  0.1 µm (fine particle composites)
    • Hybrid--blend (usually or  microfill and midifill or minifill and microfill)
  • Polymerization method
    • Auto-cured (self-cured)
    • Visible light cured
    • Dual cured
    • Staged cure
  • Matrix chemistry
    • BIS-GMA type
    • Urethane dimethacrylate (UDM or UDMA) type
    • TEGDMA-diluent monomer to reduce  viscosity

ACRYLIC RESINS

Use. Acrylic (unfilled) resins are used as temporary crown material. Temporary crowns are placed to protect the crown preparation and provide patient comfort during the time the permanent crown is being constructed

Finishing and Polishing

Remove oxygen-inhibited layer .Use stones or carbide burs for gross reduction.Use highly fluted carbide burs or special diamonds for fine reduction.Use aluminum oxide strips or disks for finishing. Use fine aluminum oxide finishing pastes. Microfills develop smoothest finish because of small size of filler particles
 

COMPOSITE RESINS

Reaction

  • Free radical polymerization

Monomers + initiator. + accelerators-+ polymer molecules

  • Initiators-start polymerization by decomposing and reacting with monomer
  • Accelerators-speed up initiator decomposition
  • Amines used  for accelerating self –curing  systems
  •  Light  used for accelerating light-curing systems

Retarders or inhibitors-prevent premature polymerization

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