Reaction

PMMA powder makes mixture viscous for manipulation before curing. Chemical accelerators cause decomposition of benzoyl peroxide into free radicals that initiate polymerization of monomer

New PMMA is formed into a matrix that surrounds PMMA powder. Linear shrinkage of 5% to 7% during setting. but dimensions of appliances are not critical

Dental Solders

Applications-bridges and orthodontic appliances

Terms

Soldering -joining operation using filler metal that melts below 500° C

Brazing -joining operation using filler metal that melts above 500°C

Welding-melting and alloying of pieces to be joined

Fluxing
 -Oxidative cleaning of area to be soldered
 - Oxygen scavenging to prevent oxidation of alloy being soldered
16- 650 -- 650 fineness solder to be used with 16-karat alloys; fineness refers to the gold content

Classification

a. Gold solders-bridges
b. Silver solders-gold-substitute bridges and orthodontic alloys

Structure of gold solders

Composition-lower gold content than of alloys being soldered

Manipulation-solder must melt below melting temperature of alloy

Properties

1. Physical-similar to alloys being joined
2. Chemical-more prone to chemical and electrochemical corrosion
3. Mechanical-similar to alloy  being joined
4. Biologic-similar to alloys being joined
 

Acrylic Denture Bases

Use - used to support artificial teeth

Classification
a. PMMA/MMA dough systems
b. PMMA/MMA pour resin systems

1. Components

a. Powder-PMMA polymer, peroxide initiator, and pigments
b. Liquid-MMA monomer, hydroquinone inhibitor, and cross-linking agents

2. Reaction
a. Heat (or chemicals) is used as an accelerator to decompose peroxide into free radicals
b. Free radicals initiate polymerization of MMA into PMMA
c. New PMMA is formed as a matrix around residual PMMA powder particles
d. Linear shrinkage is 5% to 7% of monomer on polymerization

3. Manipulation
a. P/L mixed to form dough or fluid resin to fill mold
b. Mold heated to start and control reaction

Composition of Acrylic Resins.

·        Powder. The powder is composed of a polymethyl methacrylate (PMMA), peroxide initiator, and pigments

·        Liquid. The liquid is a monomethyl methacrylate (MMA), hydroquinone inhibitor, cross-linking agents, and chemical accelerators (N, N-dimethyl-p-toluidine)

Casting ring

CASTING RING LINERS

Most common way to provide investment expansion is by using a liner in the casting ring .Traditionally asbestose was used .
Non asbestose ring liner used are :
1) Aluminosilicate ceramic liner .
2) Cellulose paper liner .

The aim of using a resilient liner is to

-. allow different types of investmentbexpansion (act as a cushion)
_. facilitate venting during casting procedure.
_. facilitate the removal of the investment block after casting.&. prevent the distortion by permitting the outward expansion of the mold.
The casting ring holds the investment in place during setting and restricts the expansion of the mold. Normally a resilient liner is placed inside the ring leaving about 2-3 mm from both ends to allow for supporting contact of the investment with the casting ring.

Purpose of Casting Ring Liner

Ringer liner is he most commonly used technique to provide investment expansion. To ensure uniform expansion , liner is cut to fit the inside diameter of the casting ring with no overlap. 

Non-asbestos Ring Liners: Ceramic (aluminum silicate) Cellulose (paper) Ceramic-cellulose combination Safety of the ceramic ring liners remains uncertain, because aluminum silicate also appears capable of producing hazardous-size respirable particles
 

Spruing Technique:

Direct Spruing:

The flow of the molten metal is straight(direct) from the casting crucible to pattern area in the ring. Even with the ball reservoir, the Spruing method is still direct. A basic weakness of direct Spruing is the potential for suck-back porosity at the junction of restoration and the Sprue.

Indirect Spruing:

Molten alloy does not flow directly from the casting crucible into the pattern area, instead the alloy takes a circuitous (indirect) route. The connector (or runner) bar is often used to which the wax pattern Sprue formers area attached. Indirect Spruing offers advantages such as greater reliability & predictability in casting plus enhanced control of solidification shrinkage .The Connector bar is often referred to as a “reservoir .

Armamentarium :
1 . Sprue
2 . Sticky wax
3 . Rubber crucible former
4 . Casting ring 
5 . Pattern cleaner 
6 . Scalpel blade & Forceps 
7 . Bunsen burner