Mercury Release in Dental Procedures Involving Amalgam

Mercury is a key component of dental amalgam, and its release during various dental procedures has been a topic of concern due to potential health risks. Understanding the amounts of mercury released during different stages of amalgam handling is essential for dental professionals to implement safety measures and minimize exposure.

1. Mercury Release Quantification

A. Trituration

• Amount Released: 1-2 µg
• Description: Trituration is the process of mixing mercury with alloy particles to form a homogenous amalgam. During this process, small amounts of mercury can be released into the air, which can contribute to overall exposure.

B. Placement of Amalgam Restoration

• Amount Released: 6-8 µg
• Description: When placing an amalgam restoration, additional mercury may be released due to the manipulation of the material. This includes the handling and packing of the amalgam into the cavity preparation.

C. Dry Polishing

• Amount Released: 44 µg
• Description: Dry polishing of amalgam restorations generates the highest amount of mercury release among the listed procedures. The friction and heat generated during dry polishing can vaporize mercury, leading to increased exposure.

D. Wet Polishing

• Amount Released: 2-4 µg
• Description: Wet polishing, which involves the use of water to cool the restoration during polishing, results in significantly lower mercury release compared to dry polishing. The water helps to capture and reduce the amount of mercury vapor released into the air.

_{Fillers in Conservative Dentistry}

_{Fillers play a crucial role in the formulation of composite resins used in conservative dentistry. They are inorganic materials added to the organic matrix to enhance the physical and mechanical properties of the composite. The size and type of fillers significantly influence the performance of the composite material.}

_{1. Types of Fillers Based on Particle Size}

_{Fillers can be categorized based on their particle size, which affects their properties and applications:}

• _{Macrofillers: 10 - 100 µm}
• _{Midi Fillers: 1 - 10 µm}
• _{Minifillers: 0.1 - 1 µm}
• _{Microfillers: 0.01 - 0.1 µm}
• _{Nanofillers: 0.001 - 0.01 µm}

_{2. Composition of Fillers}

_{The dispersed phase of composite resins is primarily made up of inorganic filler materials. Commonly used fillers include:}

• _{Silicon Dioxide}
• _{Boron Silicates}
• _{Lithium Aluminum Silicates}

_{A. Silanization}

• _{Filler particles are often silanized to enhance bonding between the hydrophilic filler and the hydrophobic resin matrix. This process improves the overall performance and durability of the composite.}

_{3. Effects of Filler Addition}

_{The incorporation of fillers into composite resins leads to several beneficial effects:}

• _{Reduces Thermal Expansion Coefficient: Enhances dimensional stability.}
• _{Reduces Polymerization Shrinkage: Minimizes the risk of gaps between the restoration and tooth structure.}
• _{Increases Abrasion Resistance: Improves the wear resistance of the restoration.}
• _{Decreases Water Sorption: Reduces the likelihood of degradation over time.}
• _{Increases Tensile and Compressive Strengths: Enhances the mechanical properties, making the restoration more durable.}
• _{Increases Fracture Toughness: Improves the ability of the material to resist crack propagation.}
• _{Increases Flexural Modulus: Enhances the stiffness of the composite.}
• _{Provides Radiopacity: Allows for better visualization on radiographs.}
• _{Improves Handling Properties: Enhances the workability of the composite during application.}
• _{Increases Translucency: Improves the aesthetic appearance of the restoration.}

_{4. Alternative Fillers}

_{In some composite formulations, quartz is partially replaced with heavy metal particles such as:}

• _Zinc
• _Aluminum
• _Barium
• _Strontium
• _Zirconium

_{A. Calcium Metaphosphate}

• _{Recently, calcium metaphosphate has been explored as a filler due to its favorable properties.}

_{B. Wear Considerations}

• _{These alternative fillers are generally less hard than traditional glass fillers, resulting in less wear on opposing teeth.}

_{5. Nanoparticles in Composites}

_{Recent advancements have introduced nanoparticles into composite formulations:}

• _{Nanoparticles: Typically around 25 nm in size.}
• _{Nanoaggregates: Approximately 75 nm, made from materials like zirconium/silica or nano-silica particles.}

_{A. Benefits of Nanofillers}

• _{The smaller size of these filler particles results in improved surface finish and polishability of the restoration, enhancing both aesthetics and performance.}

Onlay Preparation

Onlay preparations are a type of indirect restoration used to restore teeth that have significant loss of structure but still retain enough healthy tooth structure to support a restoration. Onlays are designed to cover one or more cusps of a tooth and are often used when a full crown is not necessary.

1. Definition of Onlay

A. Onlay

• An onlay is a restoration that is fabricated using an indirect procedure, covering one or more cusps of a tooth. It is designed to restore the tooth's function and aesthetics while preserving as much healthy tooth structure as possible.

2. Indications for Onlay Preparation

• Extensive Caries: When a tooth has significant decay that cannot be effectively treated with a filling but does not require a full crown.
• Fractured Teeth: For teeth that have fractured cusps or significant structural loss.
• Strengthening: To reinforce a tooth that has been weakened by previous restorations or caries.

3. Onlay Preparation Procedure

A. Initial Assessment

• Clinical Examination: Assess the extent of caries or damage to determine if an onlay is appropriate.
• Radiographic Evaluation: Use X-rays to evaluate the tooth structure and surrounding tissues.

B. Tooth Preparation

1. Burs Used:

   • Commonly used burs include No. 169 L for initial cavity preparation and No. 271 for refining the preparation.

2. Cavity Preparation:

   • Occlusal Entry: The initial occlusal entry should be approximately 1.5 mm deep.
   • Divergence of Walls: All cavity walls should diverge occlusally by 2-5 degrees:
     • 2 degrees: For short vertical walls.
     • 5 degrees: For long vertical walls.

3. Proximal Box Preparation:

   • The proximal box margins should clear adjacent teeth by 0.2-0.5 mm, with 0.5 ± 0.2 mm being ideal.

C. Bevels and Flares

1. Facial and Lingual Flares:

   • Primary and secondary flares should be created on the facial and lingual proximal walls to form the walls in two planes.
   • The secondary flare widens the proximal box, allowing for better access and cleaning.

2. Gingival Bevels:

   • Should be 0.5-1 mm wide and blend with the secondary flare, resulting in a marginal metal angle of 30 degrees.

3. Occlusal Bevels:

   • Present on the cavosurface margins of the cavity on the occlusal surface, approximately 1/4th the depth of the respective wall, resulting in a marginal metal angle of 40 degrees.

4. Dimensions for Onlay Preparation

A. Depth of Preparation

• Occlusal Depth: Approximately 1.5 mm to ensure adequate thickness of the restorative material.
• Proximal Box Depth: Should be sufficient to accommodate the onlay while maintaining the integrity of the tooth structure.

B. Marginal Angles

• Facial and Lingual Margins: Should be prepared with a 30-degree angle for burnishability and strength.
• Enamel Margins: Ideally, the enamel margins should be blunted to a 140-degree angle to enhance strength.

C. Cusp Reduction

• Cusp Coverage: Cusp reduction is indicated when more than 1/2 of a cusp is involved, and mandatory when 2/3 or more is involved.
• Uniform Metal Thickness: The reduction must provide for a uniform metal thickness of approximately 1.5 mm over the reduced cusps.
• Facial Cusp Reduction: For maxillary premolars and first molars, the reduction of the facial cusp should be 0.75-1 mm for esthetic reasons.

D. Reverse Bevel

• Definition: A bevel on the margins of the reduced cusp, extending beyond any occlusal contact with opposing teeth, resulting in a marginal metal angle of 30 degrees.

5. Considerations for Onlay Preparation

• Retention and Resistance: The preparation should be designed to maximize retention and resistance form, which may include the use of proximal retentive grooves and collar features.
• Aesthetic Considerations: The preparation should account for the esthetic requirements, especially in anterior teeth or visible areas.
• Material Selection: The choice of material (e.g., gold, porcelain, composite) will influence the preparation design and dimensions.

Hybridization in Dental Bonding

Hybridization, as described by Nakabayashi in 1982, is a critical process in dental bonding that involves the formation of a hybrid layer. This hybrid layer plays a vital role in achieving micromechanical bonding between the tooth structure (dentin) and resin materials used in restorative dentistry.

1. Definition of Hybridization

Hybridization refers to the process of forming a hybrid layer at the interface between demineralized dentin and resin materials. This phenomenon is characterized by the interlocking of resin within the demineralized dentin surface, which enhances the bond strength between the tooth and the resin.

A. Formation of the Hybrid Layer

• Conditioning Dentin: When dentin is treated with a conditioner (usually an acid), it removes minerals from the dentin, exposing the collagen fibril network and creating inter-fibrillar microporosities.
• Application of Primer: A low-viscosity primer is then applied, which infiltrates these microporosities.
• Polymerization: After the primer is applied, the resin monomers polymerize, forming the hybrid layer.

2. Zones of the Hybrid Layer

The hybrid layer is composed of three distinct zones, each with unique characteristics:

A. Top Layer

• Composition: This layer consists of loosely arranged collagen fibrils and inter-fibrillar spaces that are filled with resin.
• Function: The presence of resin in this layer enhances the bonding strength and provides a flexible interface that can accommodate stress during functional loading.

B. Middle Layer

• Composition: In this zone, the hydroxyapatite crystals that were originally present in the dentin have been replaced by resin monomers due to the hybridization process.
• Function: This replacement contributes to the mechanical properties of the hybrid layer, providing a strong bond between the dentin and the resin.

C. Bottom Layer

• Composition: This layer consists of dentin that is almost unaffected, with a partly demineralized zone.
• Function: The presence of this layer helps maintain the integrity of the underlying dentin structure while still allowing for effective bonding.

3. Importance of the Hybrid Layer

The hybrid layer is crucial for the success of adhesive dentistry for several reasons:

• Micromechanical Bonding: The hybrid layer facilitates micromechanical bonding, which is essential for the retention of composite resins and other restorative materials.
• Stress Distribution: The hybrid layer helps distribute stress during functional loading, reducing the risk of debonding or failure of the restoration.
• Sealing Ability: A well-formed hybrid layer can help seal the dentin tubules, reducing sensitivity and protecting the pulp from potential irritants.

Gallium Alloys as Amalgam Substitutes

• Gallium Alloys: Gallium alloys, such as those made with silver-tin (Ag-Sn) particles in gallium-indium (Ga-In), represent a potential substitute for traditional dental amalgam.
• Melting Point: Gallium has a melting point of 28°C, allowing it to remain in a liquid state at room temperature when combined with small amounts of other elements like indium.

Advantages

• Mercury-Free: The substitution of Ga-In for mercury in amalgam addresses concerns related to mercury exposure, making it a safer alternative for both patients and dental professionals.

Concepts in Dental Cavity Preparation and Restoration

In operative dentistry, understanding the anatomy of tooth preparations and the techniques used for effective restorations is crucial. The importance of wall convergence in Class I amalgam restorations, the use of dental floss with retainers, and specific considerations for preparing mandibular first premolars.

1. Pulpal Wall and Axial Wall

Pulpal Wall

• Definition: The pulpal wall is an external wall of a cavity preparation that is perpendicular to both the long axis of the tooth and the occlusal surface of the pulp. It serves as a boundary for the pulp chamber.
• Function: This wall is critical in protecting the pulp from external irritants and ensuring the integrity of the tooth structure during restorative procedures.

Axial Wall

• Transition: Once the pulp has been removed, the pulpal wall becomes the axial wall.
• Definition: The axial wall is an internal wall that is parallel to the long axis of the tooth. It plays a significant role in the retention and stability of the restoration.

2. Wall Convergence in Class I Amalgam Restorations

Facial and Lingual Walls

• Convergence: In Class I amalgam restorations, the facial and lingual walls should always be made slightly occlusally convergent.
• Importance:
  • Retention: Slight convergence helps in retaining the amalgam restoration by providing a mechanical interlock.
  • Prevention of Dislodgement: This design minimizes the risk of dislodgement of the restoration during functional loading.

Clinical Implications

• Preparation Technique: When preparing a Class I cavity, clinicians should ensure that the facial and lingual walls are slightly angled towards the occlusal surface, promoting effective retention of the amalgam.

3. Use of Dental Floss with Retainers

Retainer Safety

• Bow of the Retainer: The bow of the retainer should be tied with approximately 12 inches of dental floss.
• Purpose:
  • Retrieval: The floss allows for easy retrieval of the retainer or any broken parts if they are accidentally swallowed or aspirated by the patient.
  • Patient Safety: This precaution enhances patient safety during dental procedures, particularly when using matrix retainers for restorations.

Clinical Practice

• Implementation: Dental professionals should routinely tie dental floss to retainers as a standard safety measure, ensuring that it is easily accessible in case of an emergency.

4. Pulpal Wall Considerations in Mandibular First Premolars

Anatomy of the Mandibular First Premolar

• Pulpal Wall Orientation: The pulpal wall of the mandibular first premolar declines lingually. This anatomical feature is important to consider during cavity preparation.
• Pulp Horn Location:
  • The facial pulp horn is prominent and located at a higher level than the lingual pulp horn. This asymmetry necessitates careful attention during preparation to avoid pulp exposure.

Bur Positioning

• Tilting the Bur: When preparing the cavity, the bur should be tilted lingually to prevent exposure of the facial pulp horn.
• Technique: This technique helps ensure that the preparation is adequately shaped while protecting the pulp from inadvertent injury.